Electromagnetic waves carrying orbital angular momentum (OAM) can improve the spectral efficiency of communication systems by multiplexing a number of OAM modes. However, since being not able to perform water-filling power allocation and adaptive modulation for each sub-channel like closed-loop multiple-input multiple-output (MIMO) systems, the traditional orthogonal multi-mode OAM multiplexing system usually has poor bit error rate (BER) performance due to the inherent large divergence angle of high-order orthogonal OAM beams. Therefore, in this article we propose a non-orthogonal OAM (NO-OAM) multi-mode multiplexing scheme based on uniform circular array (UCA), which regulates the divergence angles of all non-orthogonal OAM beams to be the same, circumventing the problem that large beam divergence of high-order orthogonal OAM modes results in low received signal-to-noise ratio (SNR) at the receive UCA with a fixed aperture. Mathematical analysis and numerical simulations show that in contrast to the existing uniform concentric circular array (UCCA) beam adjustment scheme, the proposed NO-OAM scheme has slightly better beam adjustment effect but with only one UCA. Moreover, in contrast to the traditional orthogonal OAM multi-mode transmission, the proposed NO-OAM multi-mode multiplexing scheme has asymptotically equivalent channel capacity and much lower BER.